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• W2074367087 abstract "[email protected] bimetallic nanoparticles (NPs) catalysts were synthesized by a seeding growth method using bayberry tannin grafted collagen fiber (BT-CF) as the matrix. In this method, Au3+ was first reductively adsorbed onto BT-CF to form Au NPs, and then they serve as the seeds for the over growth of Pd shell. The morphology of [email protected] catalyst was observed by TEM and SEM, and the core–shell structure of the [email protected] was confirmed by EDS and XRD. It was found that the as-prepared BT-CF-Au9@Pd3 catalyst showed excellent synergy effect in liquid-phase hydrogenation of cyclohexene, whose reaction time was three times faster than that catalyzed by BT-CF-Pd catalyst under the same conditions. Meanwhile, the BT-CF-Au9@Pd3 catalyst could be re-used four times without significant loss of activity. In the fourth run, the substrate conversion was still as high as 92.70%, much better than that by using commercial Pd/C catalyst (42.60%). Additionally, BT-CF-Au9@Pd3 catalyst exhibited high hydrogenation activity to various alkenes and nitro-compounds. For example, the TOF of allyl alcohol, styrene and nitrobenzene hydrogenations reached 10,980, 14,732 and 1379 mol mol−1 h−1, respectively." @default.
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• W2074367087 date "2013-01-01" @default.
• W2074367087 modified "2023-09-25" @default.
• W2074367087 title "Preparation of highly active heterogeneous Au@Pd bimetallic catalyst using plant tannin grafted collagen fiber as the matrix" @default.
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• W2074367087 doi "https://doi.org/10.1016/j.molcata.2012.07.028" @default.
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