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- W2074367360 abstract "Fluorine-modified Cu/Zn/Al/Zr catalysts were prepared by calcination of the fluorine-containing Cu/Zn/Al/Zr hydrotalcite-like compounds and tested for CO2 hydrogenation to methanol. The results revealed that the CH3OH selectivity was greatly improved by the remarkable increase of the proportion of strongly basic sites, while the CO2 conversion decreased slightly. It is also found that the activity of catalysts is closely related to the synergy between the Cu and basic sites. The CH3OH yield for the fluorine-modified Cu/Zn/Al/Zr catalysts was higher than that for the fluorine-free catalysts; thus, the introduction of fluorine favored the methanol formation." @default.
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- W2074367360 date "2014-05-01" @default.
- W2074367360 modified "2023-10-18" @default.
- W2074367360 title "Fluorine-modified Cu/Zn/Al/Zr catalysts via hydrotalcite-like precursors for CO2 hydrogenation to methanol" @default.
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- W2074367360 doi "https://doi.org/10.1016/j.catcom.2014.03.006" @default.
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