FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074398410> ?p ?o ?g. }

• W2074398410 endingPage "1101" @default.
• W2074398410 startingPage "1097" @default.
• W2074398410 abstract "For p-(dimethylamino)chalcone (p-DMAC), the N atom is the most basic site in the liquid phase, whereas the O atom possesses the highest proton affinity in the gas phase. A novel and interesting observation is reported that the N- and O-protonated p-DMAC can be competitively produced in atmospheric pressure chemical ionization (APCI) with the change of solvents and ionization conditions. In neat methanol or acetonitrile, the protonation is always under thermodynamic control to form the O-protonated ion. When methanol/water or acetonitrile/water was used as the solvent, the protonation is kinetically controlled to form the N-protonated ion under conditions of relatively high infusion rate and high concentration of water in the mixed solvent. The regioselectivity of protonation of p-DMAC in APCI is probably attributed to the bulky solvent cluster reagent ions (S(n)H(+)) and the analyte having different preferred protonation sites in the liquid phase and gas phase." @default.
• W2074398410 created "2016-06-24" @default.
• W2074398410 creator A5020417364 @default.
• W2074398410 creator A5055791460 @default.
• W2074398410 creator A5057708297 @default.
• W2074398410 date "2013-04-30" @default.
• W2074398410 modified "2023-10-16" @default.
• W2074398410 title "Kinetic and Thermodynamic Control of Protonation in Atmospheric Pressure Chemical Ionization" @default.
• W2074398410 cites W1984116082 @default.
• W2074398410 cites W1984160248 @default.
• W2074398410 cites W1987540466 @default.
• W2074398410 cites W1989624708 @default.
• W2074398410 cites W1992052682 @default.
• W2074398410 cites W1994066674 @default.
• W2074398410 cites W1995668046 @default.
• W2074398410 cites W1996837894 @default.
• W2074398410 cites W1998977907 @default.
• W2074398410 cites W1999392190 @default.
• W2074398410 cites W2000393899 @default.
• W2074398410 cites W2004223088 @default.
• W2074398410 cites W2005768813 @default.
• W2074398410 cites W2008555016 @default.
• W2074398410 cites W2016770808 @default.
• W2074398410 cites W2018909650 @default.
• W2074398410 cites W2027051896 @default.
• W2074398410 cites W2034582557 @default.
• W2074398410 cites W2041558788 @default.
• W2074398410 cites W2044039308 @default.
• W2074398410 cites W2046038932 @default.
• W2074398410 cites W2052034378 @default.
• W2074398410 cites W2069006499 @default.
• W2074398410 cites W2075653168 @default.
• W2074398410 cites W2116367937 @default.
• W2074398410 cites W2146341684 @default.
• W2074398410 cites W2320888150 @default.
• W2074398410 cites W2324971132 @default.
• W2074398410 cites W2329534278 @default.
• W2074398410 cites W2952882558 @default.
• W2074398410 doi "https://doi.org/10.1007/s13361-013-0626-9" @default.
• W2074398410 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23633014" @default.
• W2074398410 hasPublicationYear "2013" @default.
• W2074398410 type Work @default.
• W2074398410 sameAs 2074398410 @default.
• W2074398410 citedByCount "29" @default.
• W2074398410 countsByYear W20743984102014 @default.
• W2074398410 countsByYear W20743984102015 @default.
• W2074398410 countsByYear W20743984102016 @default.
• W2074398410 countsByYear W20743984102017 @default.
• W2074398410 countsByYear W20743984102018 @default.
• W2074398410 countsByYear W20743984102020 @default.
• W2074398410 countsByYear W20743984102021 @default.
• W2074398410 countsByYear W20743984102023 @default.
• W2074398410 crossrefType "journal-article" @default.
• W2074398410 hasAuthorship W2074398410A5020417364 @default.
• W2074398410 hasAuthorship W2074398410A5055791460 @default.
• W2074398410 hasAuthorship W2074398410A5057708297 @default.
• W2074398410 hasConcept C145148216 @default.
• W2074398410 hasConcept C147789679 @default.
• W2074398410 hasConcept C148065180 @default.
• W2074398410 hasConcept C178790620 @default.
• W2074398410 hasConcept C179104552 @default.
• W2074398410 hasConcept C185592680 @default.
• W2074398410 hasConcept C198291218 @default.
• W2074398410 hasConcept C2777463227 @default.
• W2074398410 hasConcept C2779607525 @default.
• W2074398410 hasConcept C2780471494 @default.
• W2074398410 hasConcept C30095370 @default.
• W2074398410 hasConcept C40875361 @default.
• W2074398410 hasConcept C51884965 @default.
• W2074398410 hasConcept C75473681 @default.
• W2074398410 hasConceptScore W2074398410C145148216 @default.
• W2074398410 hasConceptScore W2074398410C147789679 @default.
• W2074398410 hasConceptScore W2074398410C148065180 @default.
• W2074398410 hasConceptScore W2074398410C178790620 @default.
• W2074398410 hasConceptScore W2074398410C179104552 @default.
• W2074398410 hasConceptScore W2074398410C185592680 @default.
• W2074398410 hasConceptScore W2074398410C198291218 @default.
• W2074398410 hasConceptScore W2074398410C2777463227 @default.
• W2074398410 hasConceptScore W2074398410C2779607525 @default.
• W2074398410 hasConceptScore W2074398410C2780471494 @default.
• W2074398410 hasConceptScore W2074398410C30095370 @default.
• W2074398410 hasConceptScore W2074398410C40875361 @default.
• W2074398410 hasConceptScore W2074398410C51884965 @default.
• W2074398410 hasConceptScore W2074398410C75473681 @default.
• W2074398410 hasIssue "7" @default.
• W2074398410 hasLocation W20743984101 @default.
• W2074398410 hasLocation W20743984102 @default.
• W2074398410 hasOpenAccess W2074398410 @default.
• W2074398410 hasPrimaryLocation W20743984101 @default.
• W2074398410 hasRelatedWork W2048398006 @default.
• W2074398410 hasRelatedWork W2074398410 @default.
• W2074398410 hasRelatedWork W2148068540 @default.
• W2074398410 hasRelatedWork W2162576361 @default.
• W2074398410 hasRelatedWork W2166118691 @default.
• W2074398410 hasRelatedWork W2367624598 @default.
• W2074398410 hasRelatedWork W2949854384 @default.
• W2074398410 hasRelatedWork W3005352396 @default.
• W2074398410 hasRelatedWork W4256357844 @default.

• next