Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074400103> ?p ?o ?g. }
- W2074400103 endingPage "4619" @default.
- W2074400103 startingPage "4614" @default.
- W2074400103 abstract "Two mesoporous ordered carbon materials (MOCs) have been synthesized from silica templates by using sucrose as the carbon precursor. The textural characterization using Ar, N2, and CO2 adsorption combined with neutron diffraction showed that the two samples exhibit a significant microporous volume close to 0.5 cm3/g and an ordered network of mesopores. For both MCM48 and SBA15 templated carbons, adsorption first proceeds with the filling of micropores and then by the filling of mesopores with an adsorption energy close to the enthalpy of vaporization of bulk hydrogen. The hydrogen isosteric heat of adsorption in the micropores (6-8 kJ/mol) is significantly larger than that on the graphite surface (approximately 4 kJ/mol) but still too small for a reasonable use of these MOCs as hydrogen adsorbents for storage at room temperature. The neutron scattering study showed that the structure at 10 K of the adsorbed deuterium phase is poorly organized; it exhibits short and medium range orders of about 13 angstroms in micropores and about 20 angstroms in mesopores, respectively. The average distance between adsorbed molecules decreases with coverage by about 10%. In the mesopores, the diffracted line is consistent with a pseudohexagonal packing." @default.
- W2074400103 created "2016-06-24" @default.
- W2074400103 creator A5004394587 @default.
- W2074400103 creator A5004479473 @default.
- W2074400103 creator A5024211132 @default.
- W2074400103 creator A5041947407 @default.
- W2074400103 creator A5064810990 @default.
- W2074400103 creator A5064998546 @default.
- W2074400103 creator A5074528205 @default.
- W2074400103 date "2006-04-04" @default.
- W2074400103 modified "2023-09-30" @default.
- W2074400103 title "Thermodynamic and Neutron Scattering Study of Hydrogen Adsorption in Two Mesoporous Ordered Carbons" @default.
- W2074400103 cites W1605790847 @default.
- W2074400103 cites W1965384177 @default.
- W2074400103 cites W1969002227 @default.
- W2074400103 cites W1970117821 @default.
- W2074400103 cites W1971239287 @default.
- W2074400103 cites W1975853685 @default.
- W2074400103 cites W1977578584 @default.
- W2074400103 cites W1977629472 @default.
- W2074400103 cites W1981502075 @default.
- W2074400103 cites W1981793726 @default.
- W2074400103 cites W1982055098 @default.
- W2074400103 cites W1982482591 @default.
- W2074400103 cites W1986505974 @default.
- W2074400103 cites W1990226499 @default.
- W2074400103 cites W2004663333 @default.
- W2074400103 cites W2010729502 @default.
- W2074400103 cites W2017878866 @default.
- W2074400103 cites W2020686937 @default.
- W2074400103 cites W2027289812 @default.
- W2074400103 cites W2028639187 @default.
- W2074400103 cites W2028755877 @default.
- W2074400103 cites W2032667425 @default.
- W2074400103 cites W2033168512 @default.
- W2074400103 cites W2034105359 @default.
- W2074400103 cites W2035180537 @default.
- W2074400103 cites W2037767143 @default.
- W2074400103 cites W2040344783 @default.
- W2074400103 cites W2066642578 @default.
- W2074400103 cites W2072953508 @default.
- W2074400103 cites W2073739354 @default.
- W2074400103 cites W2075917788 @default.
- W2074400103 cites W2076063565 @default.
- W2074400103 cites W2076238477 @default.
- W2074400103 cites W2077932431 @default.
- W2074400103 cites W2086106524 @default.
- W2074400103 cites W2142612623 @default.
- W2074400103 doi "https://doi.org/10.1021/la0527386" @default.
- W2074400103 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16649772" @default.
- W2074400103 hasPublicationYear "2006" @default.
- W2074400103 type Work @default.
- W2074400103 sameAs 2074400103 @default.
- W2074400103 citedByCount "30" @default.
- W2074400103 countsByYear W20744001032012 @default.
- W2074400103 countsByYear W20744001032015 @default.
- W2074400103 countsByYear W20744001032017 @default.
- W2074400103 countsByYear W20744001032018 @default.
- W2074400103 countsByYear W20744001032020 @default.
- W2074400103 countsByYear W20744001032022 @default.
- W2074400103 countsByYear W20744001032023 @default.
- W2074400103 crossrefType "journal-article" @default.
- W2074400103 hasAuthorship W2074400103A5004394587 @default.
- W2074400103 hasAuthorship W2074400103A5004479473 @default.
- W2074400103 hasAuthorship W2074400103A5024211132 @default.
- W2074400103 hasAuthorship W2074400103A5041947407 @default.
- W2074400103 hasAuthorship W2074400103A5064810990 @default.
- W2074400103 hasAuthorship W2074400103A5064998546 @default.
- W2074400103 hasAuthorship W2074400103A5074528205 @default.
- W2074400103 hasConcept C104015590 @default.
- W2074400103 hasConcept C104779481 @default.
- W2074400103 hasConcept C115624301 @default.
- W2074400103 hasConcept C120665830 @default.
- W2074400103 hasConcept C121332964 @default.
- W2074400103 hasConcept C127413603 @default.
- W2074400103 hasConcept C140205800 @default.
- W2074400103 hasConcept C147789679 @default.
- W2074400103 hasConcept C150394285 @default.
- W2074400103 hasConcept C159985019 @default.
- W2074400103 hasConcept C161790260 @default.
- W2074400103 hasConcept C178790620 @default.
- W2074400103 hasConcept C185592680 @default.
- W2074400103 hasConcept C191486275 @default.
- W2074400103 hasConcept C192562407 @default.
- W2074400103 hasConcept C2779698641 @default.
- W2074400103 hasConcept C42360764 @default.
- W2074400103 hasConcept C512968161 @default.
- W2074400103 hasConcept C68044625 @default.
- W2074400103 hasConcept C73585123 @default.
- W2074400103 hasConcept C8010536 @default.
- W2074400103 hasConcept C82776694 @default.
- W2074400103 hasConcept C86381522 @default.
- W2074400103 hasConceptScore W2074400103C104015590 @default.
- W2074400103 hasConceptScore W2074400103C104779481 @default.
- W2074400103 hasConceptScore W2074400103C115624301 @default.
- W2074400103 hasConceptScore W2074400103C120665830 @default.
- W2074400103 hasConceptScore W2074400103C121332964 @default.
- W2074400103 hasConceptScore W2074400103C127413603 @default.