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- W2074402077 abstract "Synthetic methods for the preparation of 3,4,5-triamino-4H-1,2,4-triazole (guanazine) and its 4-arylidene-amino derivatives are described. Guanazine, which can be used as an appropriate starting material in the syntheses of different bicyclic heterocycles, was readily obtained from thiosemicarbazide by treatment with mercuric oxide. Guanazine was also obtained from the S-methylisothio ether of thiosemicarbazide via a pyrolytic reaction. The 4-arylideneamino derivatives were either prepared by treatment of guanazine with an appropriate aromatic aldehyde, or by methods in which 1-arylidene-5-thiocarbamoyldiaminoguanidines are used as starting materials." @default.
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- W2074402077 date "1989-07-01" @default.
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- W2074402077 title "Synthesis of 3,4,5-triamino-4H-1,2,4-triazole (guanazine) and its 4-arylideneamino derivatives" @default.
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- W2074402077 doi "https://doi.org/10.1002/jhet.5570260431" @default.
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