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• W2074426516 abstract "An unprecedented class of cationic [(η6-RCO-arene)Mn(CO)3] complexes bearing resonance electron withdrawing groups have been synthesized by a high-yield two-step methodology starting from the neutral (η5-1-chlorocyclohexadienyl)Mn(CO)3 complex, employing a facile and selective transition-metal-catalyzed carbonylation followed by rearomatization. Definitive spectroscopic details of the novel [(η6-RCO-arene)Mn(CO)3]+ products are discussed, and in one case (R = PhO), the structure has been confirmed by X-ray crystallography." @default.
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• W2074426516 date "2001-07-01" @default.
• W2074426516 modified "2023-10-03" @default.
• W2074426516 title "First Synthesis of Cationic [(η⁶-arene)Mn(CO)₃] Complexes Substituted by Resonance Electron Withdrawing Groups" @default.
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• W2074426516 doi "https://doi.org/10.1021/om010162j" @default.
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