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- W2074429900 abstract "Rotationally resolved emission of NO, produced from photolysis of HNO3 at 193 nm, in the near infrared region (8900–9300 cm−1) was recorded with a step-scan Fourier-transform interferometer at a resolution of 0.1 cm−1. The emission is assigned as NO D 2Σ+−A 2Σ+ (v′,v″)=(0,0) band with rotational states N′=17–42. Emission from selective rotational states of NO D 2Σ+ was observed when HNO3 was photolyzed with an ArF excimer laser having a narrow bandwidth ≊0.01 nm. The experimental results indicate that the D 2Σ+ state of NO is formed via absorption of another 193 nm photon by NO (v″=1) in the ground electronic state. The measured distribution of intensity implies that NO is produced highly rotationally excited; the most likely mechanism for formation of NO is from the unstable NO2 fragment undergoing secondary dissociation." @default.
- W2074429900 created "2016-06-24" @default.
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- W2074429900 date "1995-09-22" @default.
- W2074429900 modified "2023-10-18" @default.
- W2074429900 title "Photodissociation of HNO<sub>3</sub> at 193 nm: Near‐infrared emission of NO detected by time‐resolved Fourier transform spectroscopy" @default.
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- W2074429900 doi "https://doi.org/10.1063/1.470623" @default.
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