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- W2074430470 abstract "Vapour pressures of water over saturated solutions of l-ascorbic acid and calcium-l-ascorbate were measured in the 280 K to 318 K temperature range and the activities of water, osmotic coefficients and the molar enthalpies of vaporization were derived from them. Densities of aqueous solutions of l-ascorbic acid, magnesium-l-ascorbate and calcium-l-ascorbate were determined at 5 K temperature intervals, from T = 288.15 K to T = 333.15 K. Densities served to evaluate the apparent molar volumes, V2,ϕ(m,T), the cubic expansion coefficients, α(m,T) and the changes of isobaric heat capacities with respect to pressure, (∂CP / ∂P)T,m. They were qualitatively correlated with the changes in the structure of water when ascorbic acid and magnesium and calcium ascorbates are dissolved in it." @default.
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- W2074430470 date "2007-03-01" @default.
- W2074430470 modified "2023-09-23" @default.
- W2074430470 title "Vapour pressure and volumetric studies in aqueous solutions with ascorbate ions" @default.
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- W2074430470 doi "https://doi.org/10.1016/j.molliq.2006.08.022" @default.
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