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- W2074444988 abstract "Porous pillared materials have been synthesized from substituted tri- and tetratitanates (Na2Ti3−xMxO7, K2Ti4−xMxO9, M=Mn, Fe, Co, Ni, Cu, x≤0.3) by a stepwise exchange process. The microstructure of pillared samples was characterized by a number of cleavages running parallel with TiO6 layers, which produced a waffle-like texture. The pillared samples showed 10–25 times larger BET surface areas (50–120 m2/g) as compared to pristine samples. The photocatalytic activity of 1 wt.% Pt/titanates for H2 evolution from CH3OH/H2O mixtures was enhanced by pillaring in accord with an increase of the surface area. Partial substitution of various transition elements for the Ti site significantly affected the H2 evolution rate." @default.
- W2074444988 created "2016-06-24" @default.
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- W2074444988 date "2000-04-01" @default.
- W2074444988 modified "2023-09-26" @default.
- W2074444988 title "Pillaring and photocatalytic property of partially substituted layered titanates, Na2Ti3−xMxO7 and K2Ti4−xMxO9 (M=Mn, Fe, Co, Ni, Cu)" @default.
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- W2074444988 doi "https://doi.org/10.1016/s1381-1169(99)00329-5" @default.
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