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- W2074453358 abstract "EuH2 has been prepared by solid–gas and EuLiH3 by solid–solid reaction. Their structures have been investigated by neutron powder diffraction on the deuterides at a wavelength close to the minimum of the neutron absorption cross-section of a natural isotope mixture of europium. EuD2 crystallises with the orthorhombic PbCl2-type structure (space group Pnma, a=623.9(2), b=379.6(1), c=719.6(2) pm, Z=4), and EuLiD3 with the cubic inverse perovskite type structure (space group Pm3̄m, a=378.75(5) pm, Z=1). Both deuterides are characterised by divalent europium and fully occupied deuterium sites. The Eu–D distances in EuD2 are 255 pm (average over 9-fold Eu co-ordination) and those in EuLiD3 are 268 pm (12-fold Eu co-ordination)." @default.
- W2074453358 created "2016-06-24" @default.
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- W2074453358 date "2000-03-01" @default.
- W2074453358 modified "2023-09-23" @default.
- W2074453358 title "The crystal structures of EuH2 and EuLiH3 by neutron powder diffraction" @default.
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- W2074453358 doi "https://doi.org/10.1016/s0925-8388(99)00818-x" @default.
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