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- W2074496985 abstract "We find the relationships among optical dielectric constant ε∞, activation energy Eac, averaged atomic mass per a formula unit, ∑jmj / N, volume V and transition temperature Tc for various type ion conductors with forms of Eac = α / (ε∞ − β), Eac = A0 + δ / [(∑jmj / N) − d], Eac = Av / V2/3, and ln(Tc) = g − hln(∑jmj), where α, β, δ, A0, d, Av, g and h are constants depending on the kinds of conduction elements. We derive those proportional forms from a simple equation of motion under the assumption of ion hopping assisted by enhanced vibration displacement of host lattice. The enhancement is induced from the large fourth-order term of the host lattice potential originating from the electronic shielding effect of Coulomb force, heavy atomic mass of constituent ion, and volume expansion under the long-range periodicity of crystal structure. This mechanism is ascertained from characteristic phenomena of various kinds of conduction elements. For impurity-type H+-ion or defect conductor, the proportional form is shifted from that of superionic conductor because of weakened effect of host lattice vibration mode on H+-ion or O-ion defect. Photo-induced spectra of mobile ion in AgCl are understood, and a small quantum effect of H+ -ion is suggested." @default.
- W2074496985 created "2016-06-24" @default.
- W2074496985 creator A5005007916 @default.
- W2074496985 date "2009-10-19" @default.
- W2074496985 modified "2023-09-25" @default.
- W2074496985 title "Ion conduction in proton- and related defect (super) ionic conductors: Mechanical, electronic and structure parameters" @default.
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- W2074496985 doi "https://doi.org/10.1016/j.ssi.2009.08.009" @default.
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