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• W2074498113 abstract "The reaction of [ReCl(μ-Cl)(COE)(CO)(NO)]2 (2) (obtained from [ReCl(μ-Cl)(CO)2(NO)] and cyclooctene (COE)) with 2,2′-bipyridine and 4,4′-dimethyl-2,2′-bipyridine leads to ReCl2(CO)L(NO) complexes (L = 2,2′-bipyridine (3), 4,4′-dimethyl-2,2′-bipyridine (4)) with trans chloride substituents. The reaction of [ReCl(μ-Cl)(CO)2(NO)]2 (1) with THF produces racemic ReCl2(CO)2(THF)(NO) (5). The Re-THF bond in 5 is labile enough to provide a primary coordination site for a bidentate ligand attack. The reaction of 2 with bpy proceeds with regioselective ReCl cleavage trans to the CO ligand and affords the ionic [ReCl(CO)2(bpy)(NO)][ReCl3(CO)2(NO)] complex 6 or, when a stoichiometric amount of NaBF4 is present, [ReCl(CO)2(bpy)(NO)][BF4] (7). The reaction of 2 with 1,2-bis(diphenylphosphino)methane (dppm) gives cis,trans-[ReCl2(η1-dppm)2(CO)(NO)] (8) while the transformation with 1,2-bis(diphenylphosphino)ethene (dppee), and NaBF4, yields an ionic [ReCl(NO)(dppee)2][BF4] compound 9. The reaction of racemic trans-1,2-bis(dimethylphosphino)cyclopentane (dmpc) with 5 proceeds with loss of the THF molecule and of one CO group, affording a diastereomeric mixture of ReCl2(CO)(dmpc)(NO) (10). The compounds 2, 4, 5, 6, 8, 9 and 10 were characterized by X-ray diffraction studies. Crystal data: 2, monoclinic, space group P21/c, a = 9.471(5), b = 10.646(6), c = 12.599(7) Å, β = 99.78(2)°, V = 1251.8(12) Å3, Z = 2; 4, monoclinic, space group C2/m, a = 13.472(4), b = 21.717(7), c = 6.491(2) Å, β = 105.33(2)°, V = 1831.7(9) Å3, Z = 4; 5, monoclinic, space group P21/n, a = 6.114(3), b = 18.443(12), c = 9.954(5) Å, β = 96.09(2)°, V = 1116.2(10) Å3, Z = 4; 6, triclinic, space group P1, a = 8.894(2), b = 10.376(2), c = 14.660(4) Å, α = 97.62(2)°, β = 97.46(2)°, γ = 102.67(2)°, V = 1290.4(6) Å3, Z = 2; 8, monoclinic, space group P21/n, a = 10.029(3), b = 30.364(9), c = 16.487(3) Å, β = 98.10(2)°, V = 4971(2) Å3, Z = 4; 9, trigonal, space group P3, a = 20.648(7), c = 11.326(4) Å, V = 4182(3) Å3, Z = 4; 10, tetragonal, space group Fdd2, a = 14.265(3), b = 50.190(10), c = 9.217(2) Å, V = 6599(2) Å3, Z = 16." @default.
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• W2074498113 date "1996-11-01" @default.
• W2074498113 modified "2023-10-17" @default.
• W2074498113 title "Synthesis of nitrosyl rhenium(I) complexes bearing bidentate ligands" @default.
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• W2074498113 doi "https://doi.org/10.1016/s0022-328x(96)06474-1" @default.
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