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- W2074515511 abstract "The reaction between a dialkyltin oxide (alkyl = CH3 or C2H5) and dilute nitric acid gives a new type of compound, the dialkyltin hydroxide nitrates R2Sn(NO3)(OH). These are stable, high-melting, crystalline substances, which are soluble in water and in methanol but insoluble in non-polar solvents. Their infrared spectra indicate that the oxygen atoms of the OH and NO3 groups are coordinated strongly with the tin atoms. The reaction of trimethyltin hydroxide with dilute nitric acid yields trimethyltin nitrate monohydrate (m.p. 98–99°), the sublimation of which gives anhydrous trimethyltin nitrate (m.p. 140°). The anhydrous compound is hygroscopic and reverts to the monohydrate upon the absorption of moisture. In anhydrous trimethyltin nitrate it is suggested that the planar trimethyltin groups are bridged by NO3 units. The most probable structure of trimethyltin nitrate monohydrate is one in which the bridged structure of the anhydrous compound is retained but with the water molecule located in the plane of the trimethyltin group and weakly coordinated to the tin atom." @default.
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- W2074515511 date "1965-01-01" @default.
- W2074515511 modified "2023-09-23" @default.
- W2074515511 title "Preparation and spectroscopic studies of dialkyltin hydroxide nitrate, trimethyltin nitrate and its monohydrate" @default.
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- W2074515511 doi "https://doi.org/10.1016/s0022-328x(00)82738-2" @default.
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