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- W2074529717 abstract "Abstract The behaviour of a binary mixture at high density can satisfactorily be described by the liquid “theories” of Prigogine and Scott. Starting from the assumption that the mixture and its components obey the law of the corresponding states it is possible to form a reduced equation of state with variables reduced with parameters of the mixture. Prigogine and Scott have proposed rules for finding these parameters. By using data from reference gases the excess enthalpy of a mixture can be calculated. The agreement between the measured and calculated values of the excess enthalpy for the mixtures CH 4 -A, CH 4 -N 2 and H 2 -CH 4 is satisfactory. However, the values from the He mixtures agree badly. The reason is that only H 2 as reference gas can be chosen, whereas in the temperature range where the data of that gas have to be found quantum effects can be expected." @default.
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- W2074529717 date "1968-09-01" @default.
- W2074529717 modified "2023-09-25" @default.
- W2074529717 title "Calculations on the excess enthalpy of the mixtures CH4-Ar, CH4-N2, H2-CH4, He-CH4 and He-Ar at high densities" @default.
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- W2074529717 doi "https://doi.org/10.1016/0031-8914(68)90030-x" @default.
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