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- W2074533182 abstract "Abstract 3‐Mercapto‐5,6‐diphenyl‐1,2,4‐triazine 1a reacts with G RIGNARD reagents to give 2b – g . 6‐Phenyl‐3‐mercapto‐5‐oxo‐4,5‐dihydro‐1,2,4‐triazine 4a reacts with phenylmagnesium bromide to form 5 , 1a and 2g . 6‐Phenyl‐3‐methylmercapto‐5‐oxo‐4,5‐dihydro‐1,2,4‐triazine 4b reacts with phenylmagnesium bromide to give 1b . Compound 1b reacts with methyl‐ and /or ethylmagnesium iodide to give 2h and 2c respectively. Compounds 1b , 4b and 2h react with hydrogen peroxide to give 6 , 7 and 3a respectively. The reactivity of the CN in position 4,5 in 1a has been further illustrated by its ready reduction with p‐thiocresol to give 2a . The action of ethereal diazomethane on 1a gives 1b ." @default.
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- W2074533182 date "1972-01-01" @default.
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- W2074533182 title "Studies on 1,2,4‐triazine derivatives. II. Reactions of Some Derivatives of 1,2,4‐Triazine with organomagnesium halides, hydrogen peroxide and p‐thiocresol" @default.
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- W2074533182 doi "https://doi.org/10.1002/prac.19723140526" @default.
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