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• W2074540182 abstract "The novel ligand 1,3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-2-pyridine, H4L, is used here for the first time. In a reaction with Co(II) it produces the complex salt [Co8O(OH)(H2L)6]NO3 (1), containing an octametallic cluster cation. The topology of this cluster, which encapsulates a rare (μ3-O)⋯H⋯(μ3-O) at its interior, exhibits a remarkable similarity to the cofactor of nitrogenase FeMoco. It features intramolecular antiferromagnetic interactions, which can be simulated using a spin-only model, yielding an S = 0 spin ground state, lying very close to numerous excited states." @default.
• W2074540182 created "2016-06-24" @default.
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• W2074540182 date "2013-04-01" @default.
• W2074540182 modified "2023-10-16" @default.
• W2074540182 title "A novel bis-β-diketonate ligand stabilizes a [Co(II)8] cage that encapsulates a (μ3-O)⋯H⋯(μ3-O) moiety" @default.
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• W2074540182 doi "https://doi.org/10.1016/j.poly.2013.02.014" @default.
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