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- W2074540881 abstract "Abstract Results of optical absorption at 300° K and 80° K of Cr 3+ ion doped in NH 4 Cl are reported. The observed bands have been assigned transitions from the ground 4 A 2g (F) state to the excited 4 T 2g (F), 2 E g (G), 2 T 1g (G) and 4 T 1g (F) states. From the nature and position of the bands a successful interpretation of all the observed bands could be made assuming tetragonal site symmetry for the Cr 3+ ion in the crystal. The crystal field parameters derived are Dq = 1480 cm −1 , Ds = −800 cm −1 , Dt = −48 cm −1 , B = 680 cm −1 and C = 3060 cm −1 . The value of 35 cm −1 , obtained for spin-orbit coupling parameter in the present work is found to be in very good agreement with the ESR value of 34 cm −1 ." @default.
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- W2074540881 date "1976-01-01" @default.
- W2074540881 modified "2023-09-27" @default.
- W2074540881 title "Absorption spectrum of Cr3+ doped in ammonium chloride single crystal" @default.
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- W2074540881 doi "https://doi.org/10.1016/s0020-1693(00)81951-9" @default.
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