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- W2074541743 abstract "The rates of oxidation of 20 heterocyclic alcohols by vanadium(V) have been measured at 60 °C in aqueous acetic acid medium in the presence of sulphuric and perchloric acid. The data indicate an overall second-order reaction at constant acid concentration, first-order each in alcohol and oxidant. The conformational effects on the rates of oxidation of various heterocyclic alcohols are discussed. An interesting observation in the present study is that t-2,t-6-diphenyl-c-3,c-5-dimethyloxan-r-4-ol, an axial alcohol, reacts slower than corresponding equatorial epimer, c-2,c-6-diphenyl-t-3,t-5-dimethyloxan-r-4-ol, which is contrary to general expectations." @default.
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- W2074541743 date "1985-01-01" @default.
- W2074541743 modified "2023-09-27" @default.
- W2074541743 title "Steric effects in the oxidation of oxan-4-ols and thian-4-ols by vanadium(V)" @default.
- W2074541743 doi "https://doi.org/10.1039/p29850001183" @default.
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