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- W2074545445 abstract "The Tl–Ba–Ca–Cu–O system has been investigated. We report on the superconducting properties and the pathway for the formation of the Tl-1223 phase and on equilibrium phase relations. The formation of Tl-1223 implies the double TlO layer phases and occurs at high temperature (890–910°C) by a progressive de-intercalation of TlO layers from Tl-2223. As a consequence of this non-equilibrium process, transient intergrowth phases may be formed and have been unambiguously identified. This path of formation results in a platelet-like morphology for Tl-1223 grains which, in the view of the fabrication of tapes, is much more interesting than the globular shape observed for (Tl,Pb)(Sr,Ba)2Ca2Cu3Oz. Moreover, the superconducting properties (Tc and irreversibility line) of the unsubstituted Tl-1223 phase compare well with those of (Tl,Pb)(Sr,Ba)2Ca2Cu3Oz. With regard to phase equilibria, we show the existence of a three phase field Tl2Ca3O6–(Tl-2212)–(Ca,Tl)1−xCuOy which prevents the formation of Tl-2223 for Tl contents higher than two." @default.
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- W2074545445 date "2001-03-01" @default.
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- W2074545445 title "Unsubstituted Tl-1223: a possible candidate for high current applications of superconductivity" @default.
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- W2074545445 doi "https://doi.org/10.1016/s0921-4534(00)01691-9" @default.
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