Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074570188> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2074570188 endingPage "383" @default.
- W2074570188 startingPage "371" @default.
- W2074570188 abstract "Kinetic equations of decomposition of several nitrobenzene (NB) derivatives were developed from isothermal DSC data. The mechanism of decomposition of all chemicals appeared to be autocatalytic with a slow first-order initiation reaction. Reaction orders, activation energies, and frequency factors of both (autocatalytic and initiation) reactions were determined for all chemicals. It was demonstrated that: utilization of a kinetic model with two parallel reactions (first-order initiation reaction and autocatalytic reaction) that have different activation energies accounts for the change in chemical behavior sometimes observed at low temperatures; reaction orders of the autocatalytic reaction are directly associated with the isothermal DSC curve shapes; elevated temperature aging of chemicals that decompose autocatalytically results in small to very significant reductions in their subsequent thermal stability." @default.
- W2074570188 created "2016-06-24" @default.
- W2074570188 creator A5012105093 @default.
- W2074570188 creator A5027338077 @default.
- W2074570188 date "2002-09-01" @default.
- W2074570188 modified "2023-09-30" @default.
- W2074570188 title "Phenomenon of autocatalysis in decomposition of energetic chemicals" @default.
- W2074570188 cites W1974369482 @default.
- W2074570188 cites W2011558164 @default.
- W2074570188 doi "https://doi.org/10.1016/s0040-6031(02)00122-3" @default.
- W2074570188 hasPublicationYear "2002" @default.
- W2074570188 type Work @default.
- W2074570188 sameAs 2074570188 @default.
- W2074570188 citedByCount "28" @default.
- W2074570188 countsByYear W20745701882013 @default.
- W2074570188 countsByYear W20745701882015 @default.
- W2074570188 countsByYear W20745701882017 @default.
- W2074570188 countsByYear W20745701882018 @default.
- W2074570188 countsByYear W20745701882019 @default.
- W2074570188 countsByYear W20745701882020 @default.
- W2074570188 countsByYear W20745701882021 @default.
- W2074570188 countsByYear W20745701882022 @default.
- W2074570188 countsByYear W20745701882023 @default.
- W2074570188 crossrefType "journal-article" @default.
- W2074570188 hasAuthorship W2074570188A5012105093 @default.
- W2074570188 hasAuthorship W2074570188A5027338077 @default.
- W2074570188 hasConcept C121332964 @default.
- W2074570188 hasConcept C121864883 @default.
- W2074570188 hasConcept C124681953 @default.
- W2074570188 hasConcept C133347239 @default.
- W2074570188 hasConcept C135502975 @default.
- W2074570188 hasConcept C135889238 @default.
- W2074570188 hasConcept C147789679 @default.
- W2074570188 hasConcept C148898269 @default.
- W2074570188 hasConcept C160434732 @default.
- W2074570188 hasConcept C161790260 @default.
- W2074570188 hasConcept C175113610 @default.
- W2074570188 hasConcept C177801218 @default.
- W2074570188 hasConcept C178790620 @default.
- W2074570188 hasConcept C185592680 @default.
- W2074570188 hasConcept C2780809723 @default.
- W2074570188 hasConcept C36663273 @default.
- W2074570188 hasConcept C37263863 @default.
- W2074570188 hasConcept C48333953 @default.
- W2074570188 hasConcept C62520636 @default.
- W2074570188 hasConcept C65024703 @default.
- W2074570188 hasConcept C93391505 @default.
- W2074570188 hasConcept C95121573 @default.
- W2074570188 hasConcept C95514000 @default.
- W2074570188 hasConcept C97355855 @default.
- W2074570188 hasConceptScore W2074570188C121332964 @default.
- W2074570188 hasConceptScore W2074570188C121864883 @default.
- W2074570188 hasConceptScore W2074570188C124681953 @default.
- W2074570188 hasConceptScore W2074570188C133347239 @default.
- W2074570188 hasConceptScore W2074570188C135502975 @default.
- W2074570188 hasConceptScore W2074570188C135889238 @default.
- W2074570188 hasConceptScore W2074570188C147789679 @default.
- W2074570188 hasConceptScore W2074570188C148898269 @default.
- W2074570188 hasConceptScore W2074570188C160434732 @default.
- W2074570188 hasConceptScore W2074570188C161790260 @default.
- W2074570188 hasConceptScore W2074570188C175113610 @default.
- W2074570188 hasConceptScore W2074570188C177801218 @default.
- W2074570188 hasConceptScore W2074570188C178790620 @default.
- W2074570188 hasConceptScore W2074570188C185592680 @default.
- W2074570188 hasConceptScore W2074570188C2780809723 @default.
- W2074570188 hasConceptScore W2074570188C36663273 @default.
- W2074570188 hasConceptScore W2074570188C37263863 @default.
- W2074570188 hasConceptScore W2074570188C48333953 @default.
- W2074570188 hasConceptScore W2074570188C62520636 @default.
- W2074570188 hasConceptScore W2074570188C65024703 @default.
- W2074570188 hasConceptScore W2074570188C93391505 @default.
- W2074570188 hasConceptScore W2074570188C95121573 @default.
- W2074570188 hasConceptScore W2074570188C95514000 @default.
- W2074570188 hasConceptScore W2074570188C97355855 @default.
- W2074570188 hasLocation W20745701881 @default.
- W2074570188 hasOpenAccess W2074570188 @default.
- W2074570188 hasPrimaryLocation W20745701881 @default.
- W2074570188 hasRelatedWork W1991959180 @default.
- W2074570188 hasRelatedWork W2002223178 @default.
- W2074570188 hasRelatedWork W2042841705 @default.
- W2074570188 hasRelatedWork W2074570188 @default.
- W2074570188 hasRelatedWork W2354653259 @default.
- W2074570188 hasRelatedWork W2355164927 @default.
- W2074570188 hasRelatedWork W2360506645 @default.
- W2074570188 hasRelatedWork W2390574183 @default.
- W2074570188 hasRelatedWork W2769360661 @default.
- W2074570188 hasRelatedWork W2789868092 @default.
- W2074570188 hasVolume "392-393" @default.
- W2074570188 isParatext "false" @default.
- W2074570188 isRetracted "false" @default.
- W2074570188 magId "2074570188" @default.
- W2074570188 workType "article" @default.