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- W2074583731 abstract "Abstract Solubilities of the disperse dyestuff 1,4-bis-(octylamino)-9,10-anthraquinone (AC08) in near- and supercritical CO 2 were measured spectroscopically in the visible range with a static analytical method. The concentrations were determined in the temperature and pressure ranges from 286 to 325 K and 6 to 90 MPa (13 isotherms). In addition, the solubility behavior was investigated along the liquid–vapor boundary curve starting at 282.5 K until near the critical temperature. As a rule, it was found that the concentrations become higher with increasing pressures and densities at a constant temperature. The isotherms of the dyestuff examined show intersection points in the concentration versus pressure plots which can be explained by a density effect. Supplementary experiments were carried out for AC08 in CClF 3 at two temperatures (309 and 315 K) and in a pressure range from 9 to 78 MPa. In this particular case higher pressures are needed to reach the same concentration as for the solvent CO 2 at a given temperature." @default.
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- W2074583731 date "1998-06-01" @default.
- W2074583731 modified "2023-09-23" @default.
- W2074583731 title "High-pressure solubility of disperse dyes in near- and supercritical fluids: measurements up to 100MPa by a static method" @default.
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- W2074583731 doi "https://doi.org/10.1016/s0896-8446(98)00032-1" @default.
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