Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074602779> ?p ?o ?g. }
Showing items 1 to 52 of
52
with 100 items per page.
- W2074602779 endingPage "1800" @default.
- W2074602779 startingPage "1800" @default.
- W2074602779 abstract "Variose, a sugar component of the antibiotic variamycin, has been identified as 2,6-dideoxy-3-O-methyl-D-ribo-hexose (i.e. D-cymarose). This assignment is based on the conversion of D-cymarose into, inter alia, methyl 2,6-dideoxy-3-O-methyl-α-D-ribo-hexofuranoside (6) and then into the 5-benzoate (8), which proved to be identical with methyl varioside benzoate. The α-cymarofuranoside (6) was also prepared by a less direct route that involved reaction of methyl 5-O-benzyl-6-deoxy-α-D-allofuranoside (10) with NN-dimethyl-α-chlorobenzylideneammonium chloride (11) to give methyl 2-O-benzoyl-5-O-benzyl-3-chloro-3,6-dideoxy-α-D-glucofuranoside (19). Reductive cleavage of the α-allo-epoxide (20) derived from (19), followed by methylation and debenzylation, gave the desired product." @default.
- W2074602779 created "2016-06-24" @default.
- W2074602779 creator A5005605324 @default.
- W2074602779 creator A5065098002 @default.
- W2074602779 creator A5087993410 @default.
- W2074602779 date "1980-01-01" @default.
- W2074602779 modified "2023-09-27" @default.
- W2074602779 title "Identification of variose as 2,6-dideoxy-3-O-methyl-D-ribo-hexose (D-cymarose)" @default.
- W2074602779 doi "https://doi.org/10.1039/p19800001800" @default.
- W2074602779 hasPublicationYear "1980" @default.
- W2074602779 type Work @default.
- W2074602779 sameAs 2074602779 @default.
- W2074602779 citedByCount "6" @default.
- W2074602779 crossrefType "journal-article" @default.
- W2074602779 hasAuthorship W2074602779A5005605324 @default.
- W2074602779 hasAuthorship W2074602779A5065098002 @default.
- W2074602779 hasAuthorship W2074602779A5087993410 @default.
- W2074602779 hasConcept C116834253 @default.
- W2074602779 hasConcept C181199279 @default.
- W2074602779 hasConcept C185592680 @default.
- W2074602779 hasConcept C2776393687 @default.
- W2074602779 hasConcept C55493867 @default.
- W2074602779 hasConcept C59822182 @default.
- W2074602779 hasConcept C71240020 @default.
- W2074602779 hasConcept C86803240 @default.
- W2074602779 hasConceptScore W2074602779C116834253 @default.
- W2074602779 hasConceptScore W2074602779C181199279 @default.
- W2074602779 hasConceptScore W2074602779C185592680 @default.
- W2074602779 hasConceptScore W2074602779C2776393687 @default.
- W2074602779 hasConceptScore W2074602779C55493867 @default.
- W2074602779 hasConceptScore W2074602779C59822182 @default.
- W2074602779 hasConceptScore W2074602779C71240020 @default.
- W2074602779 hasConceptScore W2074602779C86803240 @default.
- W2074602779 hasLocation W20746027791 @default.
- W2074602779 hasOpenAccess W2074602779 @default.
- W2074602779 hasPrimaryLocation W20746027791 @default.
- W2074602779 hasRelatedWork W1501390529 @default.
- W2074602779 hasRelatedWork W1571801152 @default.
- W2074602779 hasRelatedWork W1976751119 @default.
- W2074602779 hasRelatedWork W1996140555 @default.
- W2074602779 hasRelatedWork W2001077474 @default.
- W2074602779 hasRelatedWork W2085061074 @default.
- W2074602779 hasRelatedWork W2105068913 @default.
- W2074602779 hasRelatedWork W2131313694 @default.
- W2074602779 hasRelatedWork W2801590620 @default.
- W2074602779 hasRelatedWork W2949250458 @default.
- W2074602779 isParatext "false" @default.
- W2074602779 isRetracted "false" @default.
- W2074602779 magId "2074602779" @default.
- W2074602779 workType "article" @default.