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- W2074670783 abstract "Abstract The selectivity of a membrane toward a permeable solute is described by the reflection coefficient, which is defined as the ratio of the experimental osmotic pressure Δπ exp to its theoretical value Δπ. The systems investigated consisted of a modified cellulose acetate membrane and aqueous solutions of NaCl at various concentrations and BaCl 2 . Modification of an electronic membrane osmometer permitted direct measurements of Δπ exp at zero volume flow for such a membrane. The values of Δπ exp depend not only on the external concentrations but also on the concentration profile in the membrane established by the preceding volume flow. The significant influence of the sign and magnitude of these flows demonstrates the heterogeneity of the membrane. This memory for the volume flow history becomes manifest in Δπ exp measured at equal external concentrations. The experimental results can be interpreted semiquantitatively by describing the modified cellulose acetate membrane as a bilayer." @default.
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- W2074670783 date "1979-01-01" @default.
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- W2074670783 title "Osmotic properties of a modified cellulose acetate membrane: The reflection coefficient and its dependence on the volume flow history" @default.
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- W2074670783 doi "https://doi.org/10.1016/s0376-7388(00)80445-7" @default.
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