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- W2074688045 abstract "Single crystals of betaine phosphite and betaine phosphate were investigated in the antiferrodistortive and paraelastic phases. The comparison of the data obtained in these phases indicates an order-disorder type of phase transition. It could be shown that the two betaine molecules, which can be distinguished by 2H NMR, are located in the high-temperature phase in the mirror plane only in a statistical sense and tilt by about ±7.8° in opposite direction out of this mirror plane below the phase transition.Betainphosphit- und Betainphosphateinkristalle wurden mit Hilfe der 2H-NMR in der antiferrodistortiven und der paraelastischen Phase untersucht. Ein Vergleich der Mesergebnisse in diesen Phasen lassen auf ein Ordnungs-Unordnungs-Verhalten am Phasenubergang schliesen. Die Betainphosphat- und Betainphosphitmolekule besetzen die scheinbar entstandene Spiegelebene nur im Zeitmittel. Die Verkippung der Betainmolekule in Bezug auf die Spiegelebene betragt beim Ubergang in die antiferrodistortive Phase ungefahr ±7.8° in entgegengesetzter Richtung." @default.
- W2074688045 created "2016-06-24" @default.
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- W2074688045 date "1996-05-01" @default.
- W2074688045 modified "2023-09-26" @default.
- W2074688045 title "2H NMR studies of the antiferrodistortive phase transition in betaine phosphite and betaine phosphate" @default.
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- W2074688045 doi "https://doi.org/10.1002/pssb.2221950133" @default.
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