FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074694544> ?p ?o ?g. }

• W2074694544 endingPage "24" @default.
• W2074694544 startingPage "19" @default.
• W2074694544 abstract "The thermodynamics of the so-called perfectly polarized electrode were employed to analyze the total charge densities for a Pt(1 1 1) electrode in a series of solutions (0.1−x) M HClO4+x M KClO4 with a constant ionic strength and a variable hydronium ion concentration. The total charge densities were calculated by integration of cyclic voltammetry curves. A complete thermodynamic analysis using charge and potential as independent variables has been performed. The Gibbs excesses of adsorbed hydrogen and OH were determined without the need to introduce an arbitrary correction for the so-called charging of the double layer and further assumptions about the charge number per adsorbed species. We found that the maximum surface concentration of H amounts to ∼11×1014 ions cm−2 or to a coverage 0.73 monolayer (ML) in good agreement with previous estimates. The maximum surface coverage of OH is equal to ∼8×1014 ions cm−2 or to a coverage ∼0.53 ML. Using the thermodynamic method, the charge numbers at a constant potential (electrosorption valency) and at a constant chemical potential (reciprocal of the Esin–Markov coefficient) for adsorbed H and OH were calculated using the Gibbs excess data. The charge numbers are equal to ∼1 for H and to ∼−1 for OH. These values suggest that the adsorbed species is hydrogen atom and discharged OH species." @default.
• W2074694544 created "2016-06-24" @default.
• W2074694544 creator A5005047028 @default.
• W2074694544 creator A5019366890 @default.
• W2074694544 creator A5029352707 @default.
• W2074694544 creator A5077536025 @default.
• W2074694544 date "2003-10-01" @default.
• W2074694544 modified "2023-10-18" @default.
• W2074694544 title "Determination of the Gibbs excess of H and OH adsorbed at a Pt(111) electrode surface using a thermodynamic method" @default.
• W2074694544 cites W1606426363 @default.
• W2074694544 cites W1988078093 @default.
• W2074694544 cites W1992215614 @default.
• W2074694544 cites W1994575289 @default.
• W2074694544 cites W2002837996 @default.
• W2074694544 cites W2015750942 @default.
• W2074694544 cites W2030358382 @default.
• W2074694544 cites W2030501096 @default.
• W2074694544 cites W2032993948 @default.
• W2074694544 cites W2037621081 @default.
• W2074694544 cites W2038316306 @default.
• W2074694544 cites W2053824803 @default.
• W2074694544 cites W2059000809 @default.
• W2074694544 cites W2072609386 @default.
• W2074694544 cites W2078796196 @default.
• W2074694544 doi "https://doi.org/10.1016/s0022-0728(03)00372-3" @default.
• W2074694544 hasPublicationYear "2003" @default.
• W2074694544 type Work @default.
• W2074694544 sameAs 2074694544 @default.
• W2074694544 citedByCount "59" @default.
• W2074694544 countsByYear W20746945442012 @default.
• W2074694544 countsByYear W20746945442013 @default.
• W2074694544 countsByYear W20746945442014 @default.
• W2074694544 countsByYear W20746945442015 @default.
• W2074694544 countsByYear W20746945442016 @default.
• W2074694544 countsByYear W20746945442017 @default.
• W2074694544 countsByYear W20746945442019 @default.
• W2074694544 countsByYear W20746945442022 @default.
• W2074694544 countsByYear W20746945442023 @default.
• W2074694544 crossrefType "journal-article" @default.
• W2074694544 hasAuthorship W2074694544A5005047028 @default.
• W2074694544 hasAuthorship W2074694544A5019366890 @default.
• W2074694544 hasAuthorship W2074694544A5029352707 @default.
• W2074694544 hasAuthorship W2074694544A5077536025 @default.
• W2074694544 hasConcept C10710636 @default.
• W2074694544 hasConcept C113196181 @default.
• W2074694544 hasConcept C121332964 @default.
• W2074694544 hasConcept C138885662 @default.
• W2074694544 hasConcept C139007053 @default.
• W2074694544 hasConcept C145148216 @default.
• W2074694544 hasConcept C146477669 @default.
• W2074694544 hasConcept C147789679 @default.
• W2074694544 hasConcept C150394285 @default.
• W2074694544 hasConcept C170961132 @default.
• W2074694544 hasConcept C17525397 @default.
• W2074694544 hasConcept C178790620 @default.
• W2074694544 hasConcept C184651966 @default.
• W2074694544 hasConcept C185592680 @default.
• W2074694544 hasConcept C2777325023 @default.
• W2074694544 hasConcept C41895202 @default.
• W2074694544 hasConcept C43617362 @default.
• W2074694544 hasConcept C512968161 @default.
• W2074694544 hasConcept C55493867 @default.
• W2074694544 hasConcept C68801617 @default.
• W2074694544 hasConcept C7070889 @default.
• W2074694544 hasConcept C97355855 @default.
• W2074694544 hasConceptScore W2074694544C10710636 @default.
• W2074694544 hasConceptScore W2074694544C113196181 @default.
• W2074694544 hasConceptScore W2074694544C121332964 @default.
• W2074694544 hasConceptScore W2074694544C138885662 @default.
• W2074694544 hasConceptScore W2074694544C139007053 @default.
• W2074694544 hasConceptScore W2074694544C145148216 @default.
• W2074694544 hasConceptScore W2074694544C146477669 @default.
• W2074694544 hasConceptScore W2074694544C147789679 @default.
• W2074694544 hasConceptScore W2074694544C150394285 @default.
• W2074694544 hasConceptScore W2074694544C170961132 @default.
• W2074694544 hasConceptScore W2074694544C17525397 @default.
• W2074694544 hasConceptScore W2074694544C178790620 @default.
• W2074694544 hasConceptScore W2074694544C184651966 @default.
• W2074694544 hasConceptScore W2074694544C185592680 @default.
• W2074694544 hasConceptScore W2074694544C2777325023 @default.
• W2074694544 hasConceptScore W2074694544C41895202 @default.
• W2074694544 hasConceptScore W2074694544C43617362 @default.
• W2074694544 hasConceptScore W2074694544C512968161 @default.
• W2074694544 hasConceptScore W2074694544C55493867 @default.
• W2074694544 hasConceptScore W2074694544C68801617 @default.
• W2074694544 hasConceptScore W2074694544C7070889 @default.
• W2074694544 hasConceptScore W2074694544C97355855 @default.
• W2074694544 hasLocation W20746945441 @default.
• W2074694544 hasOpenAccess W2074694544 @default.
• W2074694544 hasPrimaryLocation W20746945441 @default.
• W2074694544 hasRelatedWork W2011354860 @default.
• W2074694544 hasRelatedWork W2028302253 @default.
• W2074694544 hasRelatedWork W2037778165 @default.
• W2074694544 hasRelatedWork W2076148711 @default.
• W2074694544 hasRelatedWork W2363030906 @default.
• W2074694544 hasRelatedWork W2510617629 @default.
• W2074694544 hasRelatedWork W2559494345 @default.
• W2074694544 hasRelatedWork W2762663192 @default.

• next