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- W2074709074 abstract "Pd nanoparticles of homogeneous size were prepared by PdCl2 reduction with hydrazine in an inverse micelle microemulsion. These Pd nanoparticles were stabilized with dodecanethiol and 3-mercaptopropyltrimethoxysilane. The latter ligands were co-condensed with tetraethylorthosilicate, yielding an amorphous, sponge-like silica framework embedding the Pd nanoparticles. The resulting [email protected]2 exhibits significant catalytic activity for the demanding Suzuki coupling of electron-rich 4-bromoanisole and phenylboronic acid. The solid can be recovered and reused with only a gradual decrease in catalytic activity. Using the cross-coupling of 4-bromoacetophenone and phenylboronic acid, a total turnover number of 63,000 was obtained. [email protected]2 can considered one of the most active phosphine-free Pd solid catalysts reported to date." @default.
- W2074709074 created "2016-06-24" @default.
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- W2074709074 date "2007-10-01" @default.
- W2074709074 modified "2023-10-18" @default.
- W2074709074 title "Pd nanoparticles embedded in sponge-like porous silica as a Suzuki–Miyaura catalyst: Similarities and differences with homogeneous catalysts" @default.
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- W2074709074 doi "https://doi.org/10.1016/j.jcat.2007.07.027" @default.
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