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- W2074759209 abstract "Phosphorus-31 and cadmium-113 NMR spectroscopy has been used to study the interaction between tertiary phosphines (P(c-C6H11)3 and PBu3) and Cd(O3SCF3)2, Cd(ClO4)2, Cd(CF3COO)2 and Cd(SCN)2 salts in solution. the NMR data imply the formation in solution of novel 1:1 adducts CdX2(phos) (X = O3SCF3, ClO4, CF3COO, phos = P(c-C6H11)3, PBu3) in which there is substantial interaction between the anions and cadmium. Data are also presented for mixed phosphine complexes CdX2[P(c-C6H11)3][PBu3] (X = O3SCF3, ClO4, NO3, CF3COO, CH3COO, Cl, Br, I, SCN). The two bond coupling constants 2J(P′P) of these mixed phosphine complexes decrease as the coordination ability of the anion increases and cover the narrow range from 95 Hz to 66 Hz." @default.
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- W2074759209 title "Phosphorus-31 and cadmium-113 NMR studies of some cadmium(II) complexes containing tricyclohexylphosphine and tributylphosphine" @default.
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- W2074759209 doi "https://doi.org/10.1016/s0020-1693(00)85233-0" @default.
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