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• W2074773086 abstract "Co-condensation of five equivalents Me2SiCl2 and one equivalent RR′SiCl2 with lithium provides the five- and six-membered rings RR′Si(Me2Si)4 and RR′Si(Me2Si)5. This method provides a direct route to the phenyl substitued methylcyclopolysilanes (R,R′  Me, Ph) which can be used for further functionalization of the silicon rings. It also provides several news sterically hindered methylcyclopolysilanes (R,R′  Ph, Ph; Me, t-Bu, t-Bu) which could not be synthesized by the conventional demethylation routes. These products have all been isolated and characterized by their ultraviolet, 1H-, 13C- and 29Si-NMR spectra." @default.
• W2074773086 created "2016-06-24" @default.
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• W2074773086 date "1982-09-01" @default.
• W2074773086 modified "2023-09-23" @default.
• W2074773086 title "Synthesis and properties of substituted methylcyclopolysilanes" @default.
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• W2074773086 doi "https://doi.org/10.1016/s0022-328x(00)86746-7" @default.
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