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- W2074778483 abstract "Abstract Interpenetrating polymer network (IPN) hydrogels composed of poly(vinyl alcohol) (PVA) and monomer, N ‐isopropylacrylamide (NIPAAm), diallyldimethylammonium chloride (DADMAC), or methacrylic acid (MAA) were prepared by using the sequential‐IPN method. The equilibrium swelling ratios of PVA/NIPAAm (VANP), PVA/DADMAC (VADC), and PVA/MAA (VAMA) are 412, 370, and 297 at 25°C, respectively. VANP had the highest swelling ratio in time‐dependent swelling behavior, whereas the swelling ratio of VAMA had the lowest. The n values of VANP, VADC, and VAMA are 0.72, 0.81, and 0.96, respectively. Transport of all IPN hydrogels is anomalous and their transport mechanisms are dominated by a combination of diffusion‐controlled and relaxation‐controlled systems. VAMA has the highest activation energy and VANP has the lowest activation energy. The values of all IPN hydrogels are from 4.66 to 16.49 kJ/mol, which proves that all IPN hydrogels are hydrophilic. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3310–3313, 2003" @default.
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- W2074778483 date "2003-10-14" @default.
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- W2074778483 title "Swelling kinetics of modified poly(vinyl alcohol) hydrogels" @default.
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- W2074778483 doi "https://doi.org/10.1002/app.13076" @default.
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