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- W2074804970 abstract "D-Glucosamine was found to undergo a condensation to give 2-(arabo-tetrahydroxybutyl)-5-(erythro-2,3,4-trihydroxybutyl)-pyrazine (2) as practically the sole product in the presence of phenylboronate or borate. The reaction proceeds in aqueous solutions at room temperature in 3 h in 58% isolated yield. In D2O solutions, the incorporation of one deuterium into the methylene group of the trihydroxybutyl arm was found. The borate esters of the product were investigated by 11B and 13C NMR spectroscopy." @default.
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- W2074804970 date "2001-10-01" @default.
- W2074804970 modified "2023-10-03" @default.
- W2074804970 title "A Clean Conversion ofD-Glucosamine Hydrochloride to a Pyrazine in the Presence of Phenylboronate or Borate" @default.
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- W2074804970 doi "https://doi.org/10.1002/1099-0690(200110)2001:20<3899::aid-ejoc3899>3.0.co;2-g" @default.
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