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• W2074807686 abstract "Three distinct ordered iodine structures on a Pt(111) surface have been studied with LEED crystallography in the coverage range 0.33–0.44 monolayers. These surfaces have translational symmetries of the [Formula: see text], [Formula: see text] and (3×3) types, and they all involve overlayer adsorption on the basically unreconstructed metal structures. The [Formula: see text] surface phase is indicated to have essentially all I atoms adsorbed at the regular threefold sites of the fcc type (i.e. 3f sites), with no significant involvement by the corresponding sites of the hcp type (i.e. 3h sites). The [Formula: see text] structure has one I on an atop Pt site, and one each at 3f and 3h sites per unit mesh, while the (3×3) surface has one I on an atop site and three on bridge sites per unit mesh. The I corrugation is about 0.5 Å for the [Formula: see text] structure, but is reduced to around 0.1 Å at the (3×3) surface. The surface I–Pt bond lengths from these analyses show a general tendency to follow trends expected with the varying I coordination numbers. A preliminary discussion is given for uncertainties associated with some relaxations indicated in the metallic structures." @default.
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• W2074807686 date "1999-10-01" @default.
• W2074807686 modified "2023-10-16" @default.
• W2074807686 title "TENSOR LEED ANALYSES FOR THREE CHEMISORBED STRUCTURES FORMED BY IODINE ON A Pt(111) SURFACE" @default.
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• W2074807686 doi "https://doi.org/10.1142/s0218625x99000937" @default.
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