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• W2074808950 abstract "By means of absorption and photoconductivity measurements, the following band gaps were found: ${mathrm{Na}}_{3}$Sb---1.1 ev; ${mathrm{K}}_{3}$Sb---1.1 ev; ${mathrm{Rb}}_{3}$Sb---1.0 ev; ${mathrm{Cs}}_{3}$Sb---1.6 ev; and ${(mathrm{NaK})}_{3}$Sb---1.0 ev. A model has been derived for the photoemission from these materials which fits the three last materials listed above in addition to the ${(mathrm{NaK})}_{3}$Sb with surface layers of Cs or Rb added. The electron affinities found from the photoemissive data using this model were as follows: ${mathrm{Rb}}_{3}$Sb---1.2 ev; ${mathrm{Cs}}_{3}$Sb---0.45 ev; ${(mathrm{NaK})}_{3}$Sb---1.0 ev; [Rb]${(mathrm{NaK})}_{3}$Sb---0.70 ev; and [Cs]${(mathrm{NaK})}_{3}$Sb---0.55 ev. The electron affinity of ${mathrm{K}}_{3}$Sb was estimated to be between 1.1 and 1.8 ev and that of ${mathrm{Na}}_{3}$Sb to be between 2.0 and 2.4 ev. By means of the temperature dependence of the photoemission, ${mathrm{Rb}}_{3}$Sb, ${mathrm{Cs}}_{3}$Sb, and the multi-alkali materials were found to have $p$-type conductivity; whereas ${mathrm{K}}_{3}$Sb and ${mathrm{Na}}_{3}$Sb were found to have $n$-type conductivity." @default.
• W2074808950 created "2016-06-24" @default.
• W2074808950 creator A5048848576 @default.
• W2074808950 date "1958-10-01" @default.
• W2074808950 modified "2023-10-10" @default.
• W2074808950 title "Photoemissive, Photoconductive, and Optical Absorption Studies of Alkali-Antimony Compounds" @default.
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• W2074808950 doi "https://doi.org/10.1103/physrev.112.114" @default.
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