Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074813550> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2074813550 endingPage "394" @default.
- W2074813550 startingPage "385" @default.
- W2074813550 abstract "Abstract Intermolecular energy transfer between the citric acid complexes of Tb(III) and Eu(III) has been used to evaluate the conditions under which the formation of polynuclear species might take place. The luminescence was followed both as a function of pH (ranging between 2 and 12), and metal/ligand ratio (working at ratios of 1:1, 1:2, 1:3, 1:5, and 1:10). Consideration of the luminescence results permitted a conclusion that all equilibria could be explained if only Ln(CIT) and Ln(CIT) 2 complexes existed under the conditions used. At the 1:1 metal/ligand ratio, extensive complex association was noted upon ionization of two of the citrate carboxyl protons. Since little hydroxide ion exists at these pH values, it would appear that the citrate ligand prefers to bind multiple metal centers while still in the bidentate bonding mode. However, upon ionization of the final carboxyl group, the associated complexes broke apart into monomeric species. At all higher ratios, the complexes were found to be monomeric at all pH values, thus indicating that the binding of two citrate ligands by a lanthanide ion (regardless of the bonding mode of the ligand) is also capable of preventing the formation of polynuclear species." @default.
- W2074813550 created "2016-06-24" @default.
- W2074813550 creator A5001224244 @default.
- W2074813550 creator A5016353081 @default.
- W2074813550 date "1983-09-01" @default.
- W2074813550 modified "2023-10-18" @default.
- W2074813550 title "Intermolecular energy transfer between lanthanide complexes. 8. Tb(III) donor and Eu(III) acceptor complexes of citric acid" @default.
- W2074813550 cites W1482089203 @default.
- W2074813550 cites W1531901161 @default.
- W2074813550 cites W1582660231 @default.
- W2074813550 cites W1978377299 @default.
- W2074813550 cites W1996405356 @default.
- W2074813550 cites W2000573689 @default.
- W2074813550 cites W2030275456 @default.
- W2074813550 cites W2055826491 @default.
- W2074813550 cites W2067028311 @default.
- W2074813550 cites W2077072069 @default.
- W2074813550 cites W2081001309 @default.
- W2074813550 cites W2082055238 @default.
- W2074813550 cites W2090645388 @default.
- W2074813550 cites W2101732941 @default.
- W2074813550 cites W3136122414 @default.
- W2074813550 cites W3137575389 @default.
- W2074813550 cites W91685575 @default.
- W2074813550 doi "https://doi.org/10.1016/0022-2313(83)90007-8" @default.
- W2074813550 hasPublicationYear "1983" @default.
- W2074813550 type Work @default.
- W2074813550 sameAs 2074813550 @default.
- W2074813550 citedByCount "12" @default.
- W2074813550 countsByYear W20748135502012 @default.
- W2074813550 countsByYear W20748135502015 @default.
- W2074813550 countsByYear W20748135502019 @default.
- W2074813550 crossrefType "journal-article" @default.
- W2074813550 hasAuthorship W2074813550A5001224244 @default.
- W2074813550 hasAuthorship W2074813550A5016353081 @default.
- W2074813550 hasConcept C106447425 @default.
- W2074813550 hasConcept C121332964 @default.
- W2074813550 hasConcept C145148216 @default.
- W2074813550 hasConcept C166950319 @default.
- W2074813550 hasConcept C178790620 @default.
- W2074813550 hasConcept C179104552 @default.
- W2074813550 hasConcept C185592680 @default.
- W2074813550 hasConcept C201770740 @default.
- W2074813550 hasConcept C26873012 @default.
- W2074813550 hasConcept C2779032678 @default.
- W2074813550 hasConcept C2779892579 @default.
- W2074813550 hasConcept C32909587 @default.
- W2074813550 hasConcept C41999313 @default.
- W2074813550 hasConcept C75473681 @default.
- W2074813550 hasConceptScore W2074813550C106447425 @default.
- W2074813550 hasConceptScore W2074813550C121332964 @default.
- W2074813550 hasConceptScore W2074813550C145148216 @default.
- W2074813550 hasConceptScore W2074813550C166950319 @default.
- W2074813550 hasConceptScore W2074813550C178790620 @default.
- W2074813550 hasConceptScore W2074813550C179104552 @default.
- W2074813550 hasConceptScore W2074813550C185592680 @default.
- W2074813550 hasConceptScore W2074813550C201770740 @default.
- W2074813550 hasConceptScore W2074813550C26873012 @default.
- W2074813550 hasConceptScore W2074813550C2779032678 @default.
- W2074813550 hasConceptScore W2074813550C2779892579 @default.
- W2074813550 hasConceptScore W2074813550C32909587 @default.
- W2074813550 hasConceptScore W2074813550C41999313 @default.
- W2074813550 hasConceptScore W2074813550C75473681 @default.
- W2074813550 hasIssue "4" @default.
- W2074813550 hasLocation W20748135501 @default.
- W2074813550 hasOpenAccess W2074813550 @default.
- W2074813550 hasPrimaryLocation W20748135501 @default.
- W2074813550 hasRelatedWork W1531901161 @default.
- W2074813550 hasRelatedWork W1964359255 @default.
- W2074813550 hasRelatedWork W2032218038 @default.
- W2074813550 hasRelatedWork W2052804580 @default.
- W2074813550 hasRelatedWork W2053238551 @default.
- W2074813550 hasRelatedWork W2074813550 @default.
- W2074813550 hasRelatedWork W2323781205 @default.
- W2074813550 hasRelatedWork W2324499501 @default.
- W2074813550 hasRelatedWork W2951036463 @default.
- W2074813550 hasRelatedWork W3138165928 @default.
- W2074813550 hasVolume "28" @default.
- W2074813550 isParatext "false" @default.
- W2074813550 isRetracted "false" @default.
- W2074813550 magId "2074813550" @default.
- W2074813550 workType "article" @default.