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- W2074820173 abstract "An effective and environmentally benign benzylic oxidation for transition of alkylarenes into the corresponding carbonyl compounds was reported. Alkylarenes were mixed and stirred with potassium bromide, m-chloroperbenzoic acid and a catalytic amount of iodobenzene in water at 60 °C for several hours, a series of the corresponding carbonyl compounds was obtained in moderate to good yields. In the reaction, iodobenzene was first oxidized by m-chloroperbenzoic acid into the hypervalent iodine intermediate which then reacted with potassium bromide to form the key radical initiator for the benzylic oxidation." @default.
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- W2074820173 date "2012-08-01" @default.
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- W2074820173 title "An environmentally benign benzylic oxidation catalyzed by hypervalent iodine intermediate in water" @default.
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- W2074820173 doi "https://doi.org/10.1016/j.cclet.2012.06.002" @default.
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