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- W2074836963 abstract "The reaction mechanism to produce the high- T c phase was investigated using X-ray powder diffractometry and thermogravimetry and differential thermal analysis (TG-DTA). The high- T c phase was produced through the low- T c phase (Bi 2 Sr 3- x Ca x Cu 2 O y , 1< x <2) which was formed as an intermediate reaction product and also as a precursor of the high- T c phase. In order to produce the high- T c phase, it is necessary that the melting point of the low- T c phase be lower than that of the high- T c phase. Increase of Ca content in the low- T c phase or decrease of ambient partial oxygen pressure during calcination are quite efficient to decrease the melting point of the low- T c phase, and hence to enhance the formation of the high- T c phase." @default.
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- W2074836963 date "1989-11-01" @default.
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- W2074836963 title "Reaction Mechanism of High-T<sub>c</sub> Phase (T<sub>c</sub>=110 K) Formation in the Bi-Sr-Ca-Cu-O Superconductive System" @default.
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