Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074837162> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2074837162 endingPage "1273" @default.
- W2074837162 startingPage "1267" @default.
- W2074837162 abstract "Die Struktur der bekannten Perchlor-3,4-pentadiensäure (5) wird durch spektroskopische und chemische Untersuchungen bestätigt. Die Säure 5 ist thermisch instabil und empfindlich gegen Wasser sowie organische Lösungsmittel. Die Verbindungen 4, 6, 8 und 9 konnten als Fragmentierungs- und Umlagerungsprodukte nachgewiesen werden. Oleum-Behandlung führt zur Oxosäure 10a. In siedendem Tetrachlorkohlenstoff dimerisiert 5 zu 13, das in Dimethylformamid zu 14 fragmentiert. Thermally Unstable Allenes, X. - Perchloro-3,4-pentadienoic Acid and Fragmentation of the Dimer into Perchloro-3,4-bis(methylene)-1-vinylcyclobutene The structure of the known perchloro-3,4-pentadienoic acid (5) has been confirmed by spectroscopic and chemical methods. The acid 5 is thermally unstable and sensitive to water and organic solvents. The compounds 4, 6, 8, and 9 could be detected as fragmentation and rearrangement products. With oleum the oxoacid 10a is formed. On heating in boiling carbon tetrachloride 5 dimerizes to 13, which is converted into 14 by fragmentation in dimethylformamide." @default.
- W2074837162 created "2016-06-24" @default.
- W2074837162 creator A5020214014 @default.
- W2074837162 creator A5052038607 @default.
- W2074837162 creator A5070079966 @default.
- W2074837162 creator A5074689699 @default.
- W2074837162 date "1977-10-19" @default.
- W2074837162 modified "2023-10-04" @default.
- W2074837162 title "Thermisch instabile Allene, X. Perchlor-3,4-pentadiensäure und Fragmentierung des Dimeren zum Perchlor-3,4-bis(methylen)-1-vinylcyclobuten" @default.
- W2074837162 cites W1966682864 @default.
- W2074837162 cites W1972980690 @default.
- W2074837162 cites W1976258933 @default.
- W2074837162 cites W1993114445 @default.
- W2074837162 cites W2007809011 @default.
- W2074837162 cites W2021040981 @default.
- W2074837162 cites W2043363461 @default.
- W2074837162 cites W2057775443 @default.
- W2074837162 cites W2065504275 @default.
- W2074837162 cites W2091294733 @default.
- W2074837162 cites W2092530544 @default.
- W2074837162 cites W2109676138 @default.
- W2074837162 cites W2112957903 @default.
- W2074837162 cites W2116824536 @default.
- W2074837162 cites W2119805773 @default.
- W2074837162 cites W2139473007 @default.
- W2074837162 cites W2143510288 @default.
- W2074837162 cites W2151050407 @default.
- W2074837162 cites W2166754552 @default.
- W2074837162 cites W2334647644 @default.
- W2074837162 cites W2582903844 @default.
- W2074837162 cites W4206171380 @default.
- W2074837162 cites W4248654867 @default.
- W2074837162 doi "https://doi.org/10.1002/jlac.197719770803" @default.
- W2074837162 hasPublicationYear "1977" @default.
- W2074837162 type Work @default.
- W2074837162 sameAs 2074837162 @default.
- W2074837162 citedByCount "8" @default.
- W2074837162 countsByYear W20748371622019 @default.
- W2074837162 crossrefType "journal-article" @default.
- W2074837162 hasAuthorship W2074837162A5020214014 @default.
- W2074837162 hasAuthorship W2074837162A5052038607 @default.
- W2074837162 hasAuthorship W2074837162A5070079966 @default.
- W2074837162 hasAuthorship W2074837162A5074689699 @default.
- W2074837162 hasConcept C111919701 @default.
- W2074837162 hasConcept C155647269 @default.
- W2074837162 hasConcept C161790260 @default.
- W2074837162 hasConcept C178790620 @default.
- W2074837162 hasConcept C185592680 @default.
- W2074837162 hasConcept C188027245 @default.
- W2074837162 hasConcept C191015642 @default.
- W2074837162 hasConcept C2777065389 @default.
- W2074837162 hasConcept C2778652500 @default.
- W2074837162 hasConcept C2779546866 @default.
- W2074837162 hasConcept C41008148 @default.
- W2074837162 hasConceptScore W2074837162C111919701 @default.
- W2074837162 hasConceptScore W2074837162C155647269 @default.
- W2074837162 hasConceptScore W2074837162C161790260 @default.
- W2074837162 hasConceptScore W2074837162C178790620 @default.
- W2074837162 hasConceptScore W2074837162C185592680 @default.
- W2074837162 hasConceptScore W2074837162C188027245 @default.
- W2074837162 hasConceptScore W2074837162C191015642 @default.
- W2074837162 hasConceptScore W2074837162C2777065389 @default.
- W2074837162 hasConceptScore W2074837162C2778652500 @default.
- W2074837162 hasConceptScore W2074837162C2779546866 @default.
- W2074837162 hasConceptScore W2074837162C41008148 @default.
- W2074837162 hasIssue "8" @default.
- W2074837162 hasLocation W20748371621 @default.
- W2074837162 hasOpenAccess W2074837162 @default.
- W2074837162 hasPrimaryLocation W20748371621 @default.
- W2074837162 hasRelatedWork W1982679802 @default.
- W2074837162 hasRelatedWork W1983082045 @default.
- W2074837162 hasRelatedWork W2024051805 @default.
- W2074837162 hasRelatedWork W2030280442 @default.
- W2074837162 hasRelatedWork W2098459911 @default.
- W2074837162 hasRelatedWork W2605672114 @default.
- W2074837162 hasRelatedWork W2949322577 @default.
- W2074837162 hasRelatedWork W2950036561 @default.
- W2074837162 hasRelatedWork W2951076518 @default.
- W2074837162 hasRelatedWork W4237823302 @default.
- W2074837162 hasVolume "1977" @default.
- W2074837162 isParatext "false" @default.
- W2074837162 isRetracted "false" @default.
- W2074837162 magId "2074837162" @default.
- W2074837162 workType "article" @default.