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- W2074850265 abstract "Reactions of triphenylsilyllithium with 1,1-dichloropropene, 2,3-dichloropropene, and 1,3-dichloropropene were investigated. The reactions of the first two compounds gave identical products: hexaphenyldisilane, triphenylsilane, 2-chloro-3-(triphenylsilyl)-propene, and 1-(triphenylsilyl)propyne. The reaction of 2-chloro-3-(triphenylsilyl)-propene and triphenylsilyllithium resulted in the formation of equal amounts of triphenylsilane and 1-(triphenylsilyl)propyne. Triphenylsilyllithium reacted with 1,3-dichloropropene in a 1:1 ratio to give hexaphenyldisilane, 1-(triphenylsilyl)-3-chloropropene, and 1-chloro-3-(triphenylsilyl)propene. The latter two compounds reacted further with triphenylsilyllithium yielding 1,3-bis(triphenylsilyl)propene. Possible mechanisms of the reactions are discussed." @default.
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- W2074850265 date "1964-10-01" @default.
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- W2074850265 title "Reactions of triphenylsilyllithium with some dichloropropenes" @default.
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- W2074850265 doi "https://doi.org/10.1016/s0022-328x(00)82214-7" @default.
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