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- W2074855824 abstract "The secondary deuterium isotope effects have been measured for the reaction between sodium thiosulphate and α-deuterated methyl, ethyl, and n-propyl bromide, and also for β- and γ-deuterated n-propyl bromide, in aqueous ethanol solvent. The α-deuterium isotopic rate ratios (k H /k D ) are all greater than unity. These unexpected results are discussed with respect to the suggested use of the α-deuterium isotope effect as a test of mechanism in nucleophilic substitutions." @default.
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- W2074855824 date "1964-04-01" @default.
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- W2074855824 title "SECONDARY KINETIC ISOTOPE EFFECTS IN BIMOLECULAR NUCLEOPHILIC SUBSTITUTIONS: I. DEUTERIUM EFFECTS IN THE BUNTE SALT REACTION" @default.
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- W2074855824 doi "https://doi.org/10.1139/v64-126" @default.
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