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- W2074865251 abstract "Existing growth mechanisms of hydrogenated amorphous silicon (a-Si:H) and microcrystalline silicon (μc-Si) assume that the growth species SiH3 can diffuse over the hydrogen-saturated Si surface. However, recent calculations suggest that this could not happen. We have carried out local density formalism pseudopotential calculations of the binding of SiH3 to hydrogen-terminated (1 1 1)Si surfaces. The bound site is not the three-centre SiHSi bridging site previously assumed. It has a direct SiSi bond between the SiH3 and the surface Si, and the surface hydrogen is displaced to a bond centre of a surface SiSi bond. A bound site validates conventional models of growth of a-Si:H and μc-Si, in which a mobile growth species creates smooth surfaces." @default.
- W2074865251 created "2016-06-24" @default.
- W2074865251 creator A5000117158 @default.
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- W2074865251 date "2003-03-01" @default.
- W2074865251 modified "2023-10-17" @default.
- W2074865251 title "Surface diffusion of SiH3 radicals and growth mechanism of a-Si:H and microcrystalline Si" @default.
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- W2074865251 doi "https://doi.org/10.1016/s0040-6090(02)01173-2" @default.
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