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- W2074889766 abstract "Truxene-acridine-1,8-dione derivatives ( Tr_AD ) are proposed as new photoinitiators of polymerization under very soft irradiation (by a household halogen lamp), as well as laser-diode exposure at 405 nm. They exhibit a strong absorption around 380 nm. The Tr_AD /diphenyl iodonium salt/9-vinylcarbazole combination is able to promote the ring-opening polymerization of an epoxide, whereas the Tr_AD /alkyl halide/amine system is very effi cient in initiating the radical photopolymerization of an acrylate. Excellent polymerization profi les are obtained. Acrylate/epoxide blends are also easily polymerized. These Tr_ADs in the three-component systems behave as photocatalysts according to oxidative cycles. The mechanisms are discussed for the different multicomponent initiating systems." @default.
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- W2074889766 date "2013-08-09" @default.
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- W2074889766 title "Novel Highly Efficient Organophotocatalysts: Truxene-Acridine-1,8-diones as Photoinitiators of Polymerization" @default.
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- W2074889766 doi "https://doi.org/10.1002/macp.201300362" @default.
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