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- W2074899994 abstract "Abstract The vibrational properties of an adsorbed atom may be studied using an exactly soluble model, in analogy with previous treatments of defects in solids, Anderson's magnetic impurities and a local vibration in a thermal bath. In this paper the delocalization of a local vibrational mode of an adatom on a crystal surface is studied for cases in which its frequency is within and outside the phonon band to which it is coupled. We use a simple treatment of the bilinear interaction between a local vibrational mode and the phonon band. The interpolation relations for the phonon field and local vibrational displacement are obtained. The localization of the phonon field at the surface is also studied. These results can be used to improve model calculations of the lineshapes of local vibrational modes at surfaces." @default.
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- W2074899994 date "1993-11-01" @default.
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- W2074899994 title "Delocalization of an adsorbate vibration and phonon localization at a surface" @default.
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- W2074899994 doi "https://doi.org/10.1016/0921-4526(93)90029-6" @default.
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