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• W2074914881 abstract "The complex shear moduli of the segmented polyurethane Estane 5703p, Livermore explosive (LX)-14, and plastic bonded explosive (PBX)-9501, which use this polymer as a binder, have been investigated. Segmented polyurethanes, such as Estane 5703, contain microphase-separated hard segments in a rubbery matrix of soft segments. LX-14 is composed of 95.5% 1,3,5,7-tetranitroazacyclooctane (HMX) explosive with 4.5% Estane 5703 binder. PBX-9501 is composed of 94.9% HMX, 2.5% Estane 5703p binder, 2.5% nitroplasticizer (NP), and about 0.1% antioxidant Irganox 1010. In the temperature range from −150 to 120°C, two relaxations were observed as peaks in the loss modulus and tangent delta in Estane 5703p and LX-14. A third relaxation was found in PBX-9501. The low temperature relaxation associated with vitrification of the poly(ester urethane) soft segment occurred in the shear loss modulus (G″) at −29 and −26°C in Estane and LX-14, respectively, at 1 Hz. In PBX-9501 the Estane soft segment glass transition peak, Tg(SS), in the loss modulus occurred at −40 ± 3°C at 1 Hz. The reduction in soft segment glass transition in PBX-9501 is clear evidence of plasticization of the soft segment by NP. The apparent activation energy of the maximum in the loss modulus for LX-14 and PBX-9501 over the frequency range from 0.1 to 10 Hz was 230 kJ/mole (55 kcal/mole). The hard segment glass transition, Tg(HS), was observed as a peak in the loss modulus at about 70°C. In LX-14 the transition was observed at lower temperatures (56–58°C at 1 Hz) depending on thermal history. There was a low temperature shoulder on the Tg(HS) of Estane 5703 associated with soft segment crystallinity. Modulated differential scanning calorimetry (MDSC) was used to verify the Tg(HS) in Estane and 50/50 mixtures of Estane with NP. In PBX-9501 the hard segment glass transition occurred between 65 and 72°C. The presence of NP in PBX-9501 gave rise to a new transition, Teu(NP), between 8 and 15°C. This peak is believed to be associated with the eutectic melting of the plasticizer. Returns of fielded PBX-9501 that were 6 and 11 years old were also measured. Small variations in Tg(SS) and the rubber plateau modulus were observed in these aged samples, consistent with migration of plasticizer and/or very low levels of chain scission. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1009–1024, 2002" @default.
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• W2074914881 date "2001-11-29" @default.
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• W2074914881 title "Dynamic mechanical signatures of a polyester-urethane and plastic-bonded explosives based on this polymer" @default.
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• W2074914881 doi "https://doi.org/10.1002/app.2281" @default.
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