FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2074915692> ?p ?o ?g. }

• W2074915692 endingPage "10544" @default.
• W2074915692 startingPage "10531" @default.
• W2074915692 abstract "Nowadays conversion-type electrode materials definitively lie as the core of any research programs related to Li-ion batteries. Requirements are high capacity, good rate capability, and a long cycle life. Indeed, the goal of much lithium battery research is to achieve the highest energy density battery as possible. In the case of pnictide materials, such performances are the results of the following conversion reaction: MxXy + 2yLi ↔ xM0 + yLi3X (X = P, Sb; M = Fe, Ni, Co, ...). However, these materials are still suffering from serious issues such as (i) low Coulombic efficiency, (ii) high polarization, (iii) poor cycle life (volume expansion), and (iv) limited rate capability that unfortunately still prevent them for any close commercial viability. In this article, the most recent research developments of our group and through collaborations in this specific field will be reported. In the interest of overcoming the limitations listed above, a cautious and rigorous scrutinizing of the electrochemical behavior of any studied materials is necessary. In our research group, we have extensive experience in the use of sophisticated in and ex situ characterization tools, in the aim to probe bulk pnictide in the Li batteries and the electrolyte/electrode surface as well. Indeed, thanks to these methods, we could unambiguously show that electrochemical conversion reactions are leading to some unstable phases, which cannot be synthesized via common chemical reaction paths. One can observe the key role of the solid/solid Li3X/M0 interfaces in the reversibility of the conversion mechanism. Contrarily, during the process, the solid/liquid electrode/electrolyte interfaces are subject to continuous parasitic reactions which drastically limit the cycle life of the battery. Fortunately, both nanostructuration of the pnictide electrodes as well as the confinement of pnictide into a porous carbon matrix play a great role in improving the performance of the cell mainly due (i) to the shortening of the distance over which Li+ diffuses or (ii) to the buffer effect of the carbon matrix against the local volume change during the charge and discharge process." @default.
• W2074915692 created "2016-06-24" @default.
• W2074915692 creator A5084397050 @default.
• W2074915692 date "2014-05-01" @default.
• W2074915692 modified "2023-10-09" @default.
• W2074915692 title "Recent Advancements in the Conversion-Type Pnictide-Based Electrodes for Li-Ion Batteries" @default.
• W2074915692 cites W1532794884 @default.
• W2074915692 cites W1593725272 @default.
• W2074915692 cites W1594672670 @default.
• W2074915692 cites W1626854854 @default.
• W2074915692 cites W1924758829 @default.
• W2074915692 cites W1967853720 @default.
• W2074915692 cites W1970206683 @default.
• W2074915692 cites W1970419887 @default.
• W2074915692 cites W1971880631 @default.
• W2074915692 cites W1975399177 @default.
• W2074915692 cites W1976226212 @default.
• W2074915692 cites W1976396059 @default.
• W2074915692 cites W1980623885 @default.
• W2074915692 cites W1985450098 @default.
• W2074915692 cites W1988907962 @default.
• W2074915692 cites W1996575716 @default.
• W2074915692 cites W1996959810 @default.
• W2074915692 cites W1997965055 @default.
• W2074915692 cites W2000304730 @default.
• W2074915692 cites W2003835747 @default.
• W2074915692 cites W2004182479 @default.
• W2074915692 cites W2005022064 @default.
• W2074915692 cites W2006527411 @default.
• W2074915692 cites W2006596215 @default.
• W2074915692 cites W2007808574 @default.
• W2074915692 cites W2009581872 @default.
• W2074915692 cites W2010390211 @default.
• W2074915692 cites W2014411652 @default.
• W2074915692 cites W2016724022 @default.
• W2074915692 cites W2019903682 @default.
• W2074915692 cites W2021981081 @default.
• W2074915692 cites W2022476971 @default.
• W2074915692 cites W2023571483 @default.
• W2074915692 cites W2023822700 @default.
• W2074915692 cites W2027207616 @default.
• W2074915692 cites W2028827573 @default.
• W2074915692 cites W2032351666 @default.
• W2074915692 cites W2034318294 @default.
• W2074915692 cites W2034855068 @default.
• W2074915692 cites W2037223441 @default.
• W2074915692 cites W2037910447 @default.
• W2074915692 cites W2038572276 @default.
• W2074915692 cites W2039263464 @default.
• W2074915692 cites W2040024770 @default.
• W2074915692 cites W2044572229 @default.
• W2074915692 cites W2045854268 @default.
• W2074915692 cites W2049824662 @default.
• W2074915692 cites W2052538732 @default.
• W2074915692 cites W2053126449 @default.
• W2074915692 cites W2054658462 @default.
• W2074915692 cites W2055064389 @default.
• W2074915692 cites W2055788521 @default.
• W2074915692 cites W2056776984 @default.
• W2074915692 cites W2056943440 @default.
• W2074915692 cites W2057129181 @default.
• W2074915692 cites W2057899803 @default.
• W2074915692 cites W2058823812 @default.
• W2074915692 cites W2059087259 @default.
• W2074915692 cites W2059550509 @default.
• W2074915692 cites W2059974204 @default.
• W2074915692 cites W2061220394 @default.
• W2074915692 cites W2067584365 @default.
• W2074915692 cites W2072366022 @default.
• W2074915692 cites W2073751755 @default.
• W2074915692 cites W2074465604 @default.
• W2074915692 cites W2075240443 @default.
• W2074915692 cites W2075903254 @default.
• W2074915692 cites W2077131294 @default.
• W2074915692 cites W2079176984 @default.
• W2074915692 cites W2083606103 @default.
• W2074915692 cites W2086278246 @default.
• W2074915692 cites W2087009376 @default.
• W2074915692 cites W2094111883 @default.
• W2074915692 cites W2095812423 @default.
• W2074915692 cites W2103790303 @default.
• W2074915692 cites W2105462414 @default.
• W2074915692 cites W2106282769 @default.
• W2074915692 cites W2117256576 @default.
• W2074915692 cites W2123405170 @default.
• W2074915692 cites W2129625348 @default.
• W2074915692 cites W2132868954 @default.
• W2074915692 cites W2137552463 @default.
• W2074915692 cites W2138285500 @default.
• W2074915692 cites W2142871469 @default.
• W2074915692 cites W2143995609 @default.
• W2074915692 cites W2163103946 @default.
• W2074915692 cites W2170212870 @default.
• W2074915692 cites W2208819737 @default.
• W2074915692 cites W2312660065 @default.
• W2074915692 cites W2315761003 @default.
• W2074915692 cites W2317443358 @default.
• W2074915692 cites W2322492516 @default.

• next