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- W2074920220 abstract "Abstract The dechlorination of chlorobenzene photosensitized by N,N-dimethyl-aniline (DMA) was studied in different solvents of varying dielectric constant and viscosity at 25°C. The extrapolated efficiency of HCl formation was determined from plots of the inverse of the quantum yield vs. the inverse of the chlorobenzene concentration. The efficiencies range from 0.25 to unity. The solvent dependence of these values was analyzed using the Eigen equation for the cage escape of the radical ion pair. From this analysis the rate constant for the in-cage fragmentation of the radical anion and back recombination of the ions were determined as 1.8 × 109 s−1 and 5.1 × 109 s−1 respectively." @default.
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- W2074920220 date "1988-10-01" @default.
- W2074920220 modified "2023-09-30" @default.
- W2074920220 title "Photoinduced electron transfer from N,N-dimethyl-aniline to chlorobenzene: The decomposition rate constant of the radical anion of chlorobenzene" @default.
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- W2074920220 doi "https://doi.org/10.1016/1010-6030(88)80111-4" @default.
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