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• W2074927834 abstract "The dynamical behavior of circular dichroism for valence photoionization processes in pure enantiomers of randomly oriented methyl-oxirane molecules has been studied by circularly polarized synchrotron radiation. Experimental results of the dichroism coefficient obtained for valence photoionization processes as a function of photon energy have been compared with theoretical values predicted by state-of-the-art ab initio density-functional theory. The circular dichroism measured at low electron kinetic energies was as large as 11%. Trends in the experimental dynamical behavior of the dichroism coefficients D(i)(omega) have been observed. Agreement between experimental and theoretical results permits unambiguous identification of the enantiomer and of the individual orbitals." @default.
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• W2074927834 date "2005-06-22" @default.
• W2074927834 modified "2023-10-17" @default.
• W2074927834 title "Valence photoionization dynamics in circular dichroism of chiral free molecules: The methyl-oxirane" @default.
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• W2074927834 doi "https://doi.org/10.1063/1.1940632" @default.
• W2074927834 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16035753" @default.
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