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- W2074930320 endingPage "9218" @default.
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- W2074930320 abstract "To gain access to prenylated hexahydroxanthenes, tandem cascade cyclization-electrophilic aromatic substitution reactions have been studied on substrates bearing allylic and propargylic substituents. Both BF3·OEt2 and TMSOTf can be used to initiate this reaction sequence, resulting in different ratios of the C-2 and C-6 substitution products. Even though allylic transposition is observed in some cases, the results of a crossover experiment are consistent with an intramolecular reaction sequence. Taken together, these studies now allow preparation of either the C-2 or C-6 prenylated hexahydroxanthene products." @default.
- W2074930320 created "2016-06-24" @default.
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- W2074930320 date "2013-11-01" @default.
- W2074930320 modified "2023-10-16" @default.
- W2074930320 title "Electrophilic aromatic prenylation via cascade cyclization" @default.
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- W2074930320 doi "https://doi.org/10.1016/j.tet.2013.08.056" @default.
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