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• W2074958674 abstract "(C5Me4H)SiMe2Cl reacts with (THF)KCH2CHCHCHCH2 to form (C5Me4H)SiMe2(CH2CHCHCHCH2) (1). Compound 1 reacts with KH and n-BuLi to make M(C5Me4)SiMe2(CH2CHCHCHCH2), M=K, 2; Li, 3, respectively. Carbon–silicon cleavage occurs when 1 reacts with K to form (C5Me4H)K, which crystallizes from dimethoxyethane as [(C5Me4H)K(DME)]x. This potassium salt has an extended structure which generates bent metallocene (C5Me4H)2K(DME) sub-structures which have 133.9° ring centroidKring centroid angles. Compound 1 reacts with TiCl4 to make (C5Me4H)TiCl3 (5), which has a piano stool structure." @default.
• W2074958674 created "2016-06-24" @default.
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• W2074958674 creator A5089479056 @default.
• W2074958674 date "2003-12-01" @default.
• W2074958674 modified "2023-10-11" @default.
• W2074958674 title "Synthesis and reactivity of a tethered diene cyclopentadiene, (C5Me4H)SiMe2(CH2CHCHCHCH2), and its alkali metal salts" @default.
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• W2074958674 doi "https://doi.org/10.1016/j.jorganchem.2003.09.013" @default.
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