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- W2074964980 abstract "Abstract The recent advance of the aromaticity concept into the all-metal species enlightens us to explore whether all-metal aromatic system Al 4 2 - can adsorb small gas molecule on its surface. Y ( Y = Al 4 2 - , LiAl 4 - and Li 2 Al 4 ) and X (X = H 2 , N 2 , O 2 , F 2 , Cl 2 , Br 2 , CO and SO) were chosen for this purpose. When interacting with X, the similarities and differences between all-metal aromatic system Al 4 2 - / LiAl 4 - / Li 2 Al 4 and organic aromatic systems were discussed. Some special phenomena of Y⋯X induced by the characteristic of Al 4 2 - were investigated, which may give a base for the future research on the potential catalysis of these complexes." @default.
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- W2074964980 date "2004-10-01" @default.
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- W2074964980 title "Theoretical study on all-metal aromatic complexes: interaction with small gas molecule" @default.
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- W2074964980 doi "https://doi.org/10.1016/j.cplett.2004.08.116" @default.
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