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- W2074967292 abstract "Rheological measurements are used to monitor the sol-gel behavior of a superconducting precursor. A precursor made with an aged yttrium component [Y(OH)3] has a much higher elastic modulus (G′) and complex viscosity (η*) but the same loss modulus (G″) compared to that made with a fresher yttrium solution. The G″/G′ ratio is less than unity for the older solution but greater than 1 for the fresher sample, indicating that the former solution has a more gel-like character. The high viscosity sample gives better fired thick-film superconducting properties but has a shorter shelf life. Measurements on yttrium components of different age show differences in viscosity and G″/G′ which correlate with the behavior of the oxide precursors. Reshearing the precursor solution at any stage during its gelation process can cause irreversible changes in the gel structure." @default.
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- W2074967292 date "1988-08-22" @default.
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- W2074967292 title "Rheological study of a gel‐forming precursor for superconducting YBa2Cu3O7−x" @default.
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- W2074967292 doi "https://doi.org/10.1063/1.100645" @default.
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