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• W2074967488 abstract "The first-order thermal transitions including side-chain melting, crystal-LC, biphasic chimney-like, and isotropic transitions of poly(n-undecyl isocyanate) (PUDIC) were investigated by varying its thermal history. After annealing at 140 °C for different periods of time, it leads to different degrees of backbiting degradation into n-undecyl isocyanurate trimer which behaves as a solvent for the rest non-degraded/rigid PUDIC to change into a lyotropic LC from thermotropic transition. Based on the degree of degradation, various amounts of trimers are present and the PUDIC demonstrates different types of thermal transitions found in DSC thermograms due to the variation of the non-degraded PUDIC concentration in solvent trimers. Finally, a phase diagram includes all types of crystallines, LC, and isotropic regions can be drawn according to the DSC thermograms." @default.
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• W2074967488 date "2008-05-01" @default.
• W2074967488 modified "2023-09-28" @default.
• W2074967488 title "Degradation induced variation of LC transition of poly(n-undecyl isocyanate)" @default.
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• W2074967488 doi "https://doi.org/10.1016/j.polymdegradstab.2008.01.032" @default.
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